研究業績

研究項目

カテゴリ

2022
原著論文

Effects of Conformation on Doping Efficiency in π-Extended Bipyranylidene Molecules: Relationship between Molecular Structure and Electron-Doping Ability for Developing n-Type Organic Thermoelectrics

Bull. Chem. Soc. Jpn., 2022, in press.

10.1246/bcsj.20220124

Large Enhancement of Single Molecular Conductance of Molecular Wire through a Radical Substituent

Chem. Eur. J., 2022, 28, e202104242.

10.1002/chem.202104242

Doubly linked chiral phenanthrene oligomers for homogeneously π-extended helicenes with large effective conjugation length

Nat. Commun., 2022, 13, 1475.

10.1038/s41467-022-29108-8

Comparison of the charge-crystal and charge-glass state in geometrically frustrated organic conductors studied by fluctuation spectroscopy

Phys. Rev. B, 2022, 105, 205111.

10.1103/PhysRevB.105.205111

Hybrid Chiral MoS2 Layers for Spin-polarized Charge Transport and Spin-dependent Electrocatalytic Applications

Adv. Sci., 2022, in press.

10.1002/advs.202201063

Solid-State Assembly by Chelating Chalcogen Bonding in Quinodimethane Tetraesters Fused with a Chalcogenadiazole

ChemPlusChem, 2022, 87, e202200075.

10.1002/cplu.202200075

Chalcogen Bond versus Halogen Bond: Changing Contributions in Determining the Crystal Packing of Dihalobenzochalcogenadiazoles

Bull. Chem. Soc. Jpn., 2022, 95, 522–531.

10.1246/bcsj.20220008

Copper(II) Complexes of 10,20-Diaryl-5,15-diazaporphyrin: Alternative Synthesis, Excited State Dynamics, and Substituent Effect on the 1O2-Generation Efficiency

Bull. Chem. Soc. Jpn., 2022, 95, 427–432.

10.1246/bcsj.20220002

Spatiotemporal dynamics of supramolecular polymers by in situ quantitative catalyst-free hydroamination

Chem. Sci., 2022, 13, 4413–4423.

10.1039/D2SC00035K

Synthesis of π-Extended Thiele’s and Chichibabin’s Hydrocarbons and Effect of the π-Congestion on Conformations and Electronic States

J. Am. Chem. Soc., 2022, 144, 7479–7488.

10.1021/jacs.2c02318

Synthesis and Tautomerization of 5-Azaporphyrinium Cations

Chem. Lett., 2022, in press.

10.1246/cl.220122

Chiral Supramolecular Polymer Formed via Host-Guest Complexation of an Octaphosphonate Biscavitand and a Chiral Diammonium Guest

Bull. Chem. Soc. Jpn., 2022, 95, 621–627.

10.1246/bcsj.20210452

5-Thiaporphyrinium Cation: Effect of Sulphur Incorporation on Excited State Dynamics

Chem. Commun., 2022, 58, 5956–5959.

10.1039/D2CC00522K

Formation of a Two-Dimensional Electronic System in Laterally Assembled WTe Nanowires

ACS Appl. Nano Mater., 2022, in press.

10.1021/acsanm.2c00377

Tunable Solid-State Thermochromism: Alkyl Chain Length-Dependent Conformational Isomerization of Bianthrones

Chem. Asian J., 2022, in press.

10.1002/asia.202200121

Sterically Frustrated Aromatic Enes with Various Colors Originating from Multiple Folded and Twisted Conformations in Crystal Polymorphs

Chem. Eur. J., 2022, 28, e202200286.

10.1002/chem.202200286

A carbon-functionality-appended diborylacetylene available for a component of organic synthesis and OLEDs

Chem. Commun., 2022, 58, 4973–4976.

10.1039/D2CC01159J

Microscopic observation of efficient intergrain charge transport processes in organic transistors of semicrystalline poly(3-hexylthiophene)

Appl. Phys. Express, 2022, 15, 041004.

10.35848/1882-0786/ac5d79

Diverse Crystal Structures of Ion Pairs Consisting of Oxaporphyrinium Cations and Pentacyanocyclopentadienide

Bull. Chem. Soc. Jpn., 2022, 95, 796–801.

10.1246/bcsj.20220026

Host-Guest Complexation of Bisporphyrin Cleft and Electron-Deficient Aromatic Guests

J. Org. Chem., 2022, 87, 4001–4009.

10.1021/acs.joc.1c02742

Transient chirality inversion during racemization of a helical cobalt(III) complex

Proc. Natl. Acad. Sci. USA, 2022, 119, e2113237119.

10.1073/pnas.2113237119

Band-like versus temperature-independent carrier transport in isomeric diphenyldinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophenes (DPh-DNTTs)

ACS Materials Lett., 2022, 4, 675–681.

10.1021/acsmaterialslett.2c00084

Large Enhancement of Single Molecular Conductance of Molecular Wire by a Radical Substituent

Chem. Eur. J., 2022, 28, e202104242.

10.1002/chem.202104242

A Fully Conjugated Porphyrin–[36]Octaphyrin–Porphyrin Hybrid Tape Exhibiting Möbius Aromaticity

Chem. Eur. J., 2022, 28, e202200328.

10.1002/chem.202200328

Synthesis, Properties and Chemical Modification of a Persistent Triisopropylsilylethynyl Substituted Tri(9-anthryl)methyl Radical

Chem. Commun., 2022, 58, 3306–3309.

10.1039/D2CC00548D

A dicyanomethyl radical stabilized by ferrocene: a new building block for radical-based dynamic covalent chemistry with redox activity

Chem. Commun., 2022, 58, 3553–3556.

10.1039/D1CC07253F

A strong hydride donating, acid stable and reusable 1,4-dihydropyridine for selective aldimine and aldehyde reductions

Org. Bio. Chem., 2022, 20, 1671–1679.

10.1039/d1ob02358f

Magnetic Torque due to Anisotropic Diamagnetism in Neutral BEDT-TTF Crystals

J. Phys. Soc. Jpn., 2022, 90, 113708.

10.7566/JPSJ.90.113708

Tuning the Parity Mixing of Singlet-Septet Pairing in a Half-Heusler Superconductor

Phys. Rev. X, 2022, 11, 041048.

10.1103/PhysRevX.11.041048

Nanowire-to-Nanoribbon Conversion in Transition-Metal Chalcogenides: Implications for One-Dimensional Electronics and Optoelectronics

ACS Appl. Nano Mater., 2022, 5, 1775–1782.

10.1021/acsanm.1c03160

Thermodynamic evidence for a field-angle-dependent Majorana gap in a Kitaev spin liquid

Nat. Phys., 2022, 18, 429–435.

10.1038/s41567-021-01488-6

Involvement of structural dynamics in charge-glass formation in strongly frustrated molecular metals

Phys. Rev. B, 2022, 105, L041114.

10.1103/PhysRevB.105.L041114

Dibenzodiazapyracylenes: Doubly N-Doped Cyclopenta-fused Polycyclic Molecules That Exhibit High Carrier Mobility

Angew. Chem. Int. Ed., 2022, 61, e202200341.

10.1002/anie.202200341

Bridging pico-to-nanonewtons with a ratiometric force probe for monitoring nanoscale polymer physics before damage

Nat. Commun., 2022, 13, 303.

10.1038/s41467-022-27972-y

Ratiometric Flapping Force Probe That Works in Polymer Gels

J. Am. Chem. Soc., 2022, 144, 2804–2815.

10.1021/jacs.1c12955

Probing a microviscosity change at the nematic-isotropic liquid crystal phase transition by a ratiometric flapping fluorophore

Chem. Commun., 2022, 58, 2128–2131.

DOI: 10.1039/d1cc06111a

On-Surface Synthesis of Porphyrin-Complex Multi-Block Co-Oligomers by Defluorinative Coupling

Angew. Chem. Int. Ed., 2022, 61, e202114697.

10.1002/anie.202114697

Molecular and Spin Structures of a Through-Space Conjugated Triradical System

Angew. Chem. Int. Ed., 2022, 61, e202200688.

10.1002/anie.202200688

Anthraquinodimethane Ring-Flip in Sterically Congested Alkenes: Isolation of Isomer and Elucidation of Intermediate through Experimental and Theoretical Approach

Bull. Chem. Soc. Jpn., 2022, 95, 38–46.

10.1246/bcsj.20210355

Nitrogen Extrusion of Diazacorrphycenes to Azacorroles and Synthesis of Two Types of Copper 10-Azacorrole Complexes

Chem. Lett., 2022, 51, 321–324.

10.1246/cl.210777

Late-Stage Modification of π-Electron Systems Based on Asymmetric Oxidation of Medium-Sized Sulfur-Containing Ring

Chem. Commun., 2022, 58, 2548–2551.

10.1039/D1CC06996A

Synthesis and optical properties of disiloxane-linked decathiophene and dodecathiophene polymers

Polym. J., 2022, 54, 91–96.

10.1038/s41428-021-00541-8

Mechanism and Kinetics of Fluorescence Quenching of Fluorene-Endcapped Butatriene: A Microspectroscopic Study of the Discrete State Constructed in Microcrystals

J. Phys. Chem. C, 2022, 126, 1196–1203.

10.1021/acs.jpcc.1c09163

Isolation and Structure Analysis of a Ni(II) Norcorrole Radical Anion

Chem. Lett., 2022, 51, 182–184.

10.1246/cl.210715

Fold-in Synthesis of a Pentabenzopentaaza[10]circulene

Angew. Chem. Int. Ed., 2022, 61, e202116789.

10.1002/anie.202116789

A Supramolecular Polymer Constituted of Antiaromatic Ni(II) Norcorroles

Angew. Chem. Int. Ed., 2022, 61, e202114230.

10.1002/anie.202114230

A Heme-Acquisition Protein Reconstructed with a Cobalt 5-Oxaporphyrinium Cation and Its Growth-Inhibition Activity Toward Multidrug-Resistant Pseudomonas aeruginosa

Angew. Chem. Int. Ed., 2022, 61, e202112456.

10.1002/anie.202112456

Metallic Conduction and Carrier Localization in Two-Dimensional BEDO-TTF Charge-Transfer Solid Crystals

Crystals, 2022, 12, 23.

10.3390/cryst12010023

1,2,3-Tri(9-anthryl)benzene: Photophysical Properties and Solid-State Intermolecular Interactions of Radially Arranged, Congested Aromatic π-Planes

Chem. Eur. J., 2022, 28, e202104245.

10.1002/chem.202104245

Enantiopure 2-(2-ethylhexyl)dinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophenes: synthesis, single crystal-structure and surprising lack of influence of stereoisomerism on thin-film structure and electronic properties

Mater. Horiz., 2022, 9, 444−451.

10.1039/D1MH01119G

Packing structures of (trialkylsilyl)ethynyl-substituted dinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophenes (DNTTs): effects of substituents on crystal structures and transport properties

J. Mater. Chem. C, 2022, 10, 2775−2782.

10.1039/D1TC04312A

Five-fold Symmetric Pentaindolo- and Pentakis(benzoindolo)-Corannulenes: Unique Structural Dynamics Derived from the Combination of Helical- and Bowl-Inversions

Angew. Chem. Int. Ed., 2022, 61, e202112589.

10.1002/anie.202112589

One-Shot Synthesis of Expanded Heterohelicene Exhibiting Narrowband Thermally Activated Delayed Fluorescence

J. Am. Chem. Soc., 2022, 144, 106–112.

10.1021/jacs.1c11659

Tetraaryldiborane(4) Can Emit Dual Fluorescence Responding to the Structural Change around the B–B Bond

Angew. Chem. Int. Ed., 2022, 61, e202113549.

10.1002/anie.202113549
招待講演

ホウ素の空軌道エンジニアリングに基づく物質開発

特異な電子構造と安定性をあわせもつ新奇π電子系の創成

著書・総説・解説

Redox-Active Hydrocarbons: Isolation and Structural Determination of Cationic States toward Advanced Response Systems

Recent Advances in the Syntheses of Oxidized and Reduced Porphyrins

Bringing out the potential of organoboron compounds by designing the chemical bonds and spaces around boron

Synthesis of Novel Heteronanographenes via Fold-in Approach

Resorcinarene-based Supramolecular Capsules – Supramolecular Functions and Applications

Nanographene – A Scaffold of Two-Dimensional Materials