研究業績

研究項目

カテゴリ

2023
原著論文

Effect of Internal Substituents on the Properties of Dibenzo[g,p]chrysene

Org. Lett., 2023, 25, 8484–8488.

10.1021/acs.orglett.3c03428

Effect of Internal Oxygen Substituents on the Properties of Bowl-Shaped Aromatic Hydrocarbons

Org. Chem. Front. , 2023, 10, 5895–5901.

10.1039/D3QO01661G

A Memristive Oscillator

Adv. Physics Res.,2023, in press.

10.1002/apxr.202300117

A dodecamethoxy[6]cycloparaphenylene consisting entirely of hydroquinone ethers: unveiling in-plane aromaticity through a rotaxane structure

Nat. Commun., 2023, 14, 8091.

10.1038/s41467-023-43907-7

Fulde-Ferrell-Larkin-Ovchinnikov state induced by antiferromagnetic order in κ-type organic conductors

Phys. Rev. Research, 2023, 5, 043171.

10.1103/PhysRevResearch.5.043171

Domino-Redox Reaction Induced by An Electrochemically Triggered Conformational Change

Angew. Chem. Int. Ed., 2023, 63, e202316753.

10.1002/anie.202316753

Verdazyl–Nitroxide Diradical with S = 1 Ground State: Observation of Long-Range Ordering and Haldane Gap in a Highly Isotropic S = 1 Antiferromagnetic Heisenberg Chain

J. Phys. Chem. C, 2023, 127, 21822–21828.

10.1021/acs.jpcc.3c05584

Crystal-structure simulation of molecular semiconductors: brickwork-related crystal structures of methylthiolated peri-condensed polycyclic aromatic hydrocarbons

Mater. Horiz., 2023, 10, 5492–5499.

10.1039/D3MH01055D

Acceleration and deceleration of chirality inversion speeds in a dynamic helical metallocryptand by alkali metal ion binding

Sci. Adv., 2023, 9, eadj5536.

10.1126/sciadv.adj5536

Synthesis of closed-Heterohelicenes Interconvertible between Its Monomeric and Dimeric Forms

Angew. Chem. Int. Ed., 2023, 62, e202314968.

10.1002/anie.202314968

Stapling strategy for slowing helicity interconversion of α-helical peptides and isolating chiral auxiliary-free one-handed forms

Nat. Commun., 2023, 14, 6834.

10.1038/s41467-023-42493-y

Doping of molecular semiconductors through proton-coupled electron transfer

Nature, 2023, 622, 285–291.

10.1038/s41586-023-06504-8

Vis-NIR-Electrochromic Interconversion of Dithienylmethylium-type Cyanine Dyes with a σ-Bonded Dimer or Isolable Neutral Radical

Bull. Chem. Soc. Jpn., 2023, 96, 1144–1149.

10.1246/bcsj.20230169

Double Dynamic Structural Change Enabling Tricolor Chromism by the Realization of Apparent Two-Electron Transfer to Skip the Open-Shell State

Chem. Eur. J., 2023, 29, e202301476.

10.1002/chem.202301476

Chalcogen-Peierls Transition: Single-Crystal-to-Single-Crystal Transition from a Two-Dimensional to a One-Dimensional Network of Chalcogen Bonds at Low Temperature

Bull. Chem. Soc. Jpn., 2023, 96, 631–635.

10.1246/bcsj.20230091

One-Pot Synthesis of Helical Azaheptalene and Chiroptical Switching of an Isolable Radical Cation

Chem. Eur. J., 2023, 29, e202301759.

10.1002/chem.202301759

Pressure-Responsive Polymer Chemosensors for Hydrostatic-Pressure-Signal Detection: Poly-L-Lysine-Pyrene Conjugates

ACS Macro Lett., 2023, 12, 1389–1395.

10.1021/acsmacrolett.3c00427

Valley polarization dependence of nonreciprocal transport in a chiral semiconductor

Phys. Rev. B, 2023, 108, 125137.

10.1103/PhysRevB.108.125137

Chiral Van Der Waals Superlattices for Enhanced Spin‐Selective Transport and Spin‐Dependent Electrocatalytic Performance

Adv. Mater., 2023, 35, 2306061.

10.1002/adma.202306061

Bidipyrrin AuIII Complex as a Helical Charged π-Electronic System

Org. Lett., 2023, 25, 6040–6045.

10.1021/acs.orglett.3c02214

Borylated β-Fluorinated Pyrroles

Chem. Lett. , 2023, 52, 598–601.

10.1246/cl.230201

Ion-Pairing Assemblies of Dithienylnitrophenol-Based π-Electronic Anions Stabilized by Intramolecular Interactions

Org. Lett., 2023, 25, 3676–3681.

10.1021/acs.orglett.3c01075

Synthesis and Characterization of Dibenzothieno[a,f]pentalenes Enabling Large Antiaromaticity and Moderate Open-Shell Character through a Small Energy Barrier for Bond-Shift Valence Tautomerization

J. Am. Chem. Soc., 2023, 145, 20595–20609.

10.1021/jacs.3c07356

Quinoidal Acenedichalcogenophenediones for Near-Infrared-Absorbing Organic Semiconductors: Effects of Chalcogen Atom Substitution on the Physicochemical and Carrier Transport Properties

Chem. Mater. , 2023, 35, 7628–7642.

10.1021/acs.chemmater.3c01350

Direct observations of spin fluctuations in hedgehog–anti-hedgehog spin lattice states in MnSi1−xGex (x = 0.6 and 0.8) at zero magnetic field

Phys. Rev. B, 2023, 108, 054445.

10.1103/PhysRevB.108.054445

Crystal-structure simulation of methylthiolated peri-condensed polycyclic aromatic hydrocarbons for identifying promising molecular semiconductors: discovery of 1,3,8,10-tetrakis(methylthio)peropyrene showing ultrahigh mobility

Adv. Mater., 2023, 35, 2305548.

10.1002/adma.202305548

Contrasted behaviours of methylthiolated perylene and pyrene as organic semiconductors: implications of molecular electronic structure and crystal structure

J. Mater. Chem. C, 2023, 11, 10809–10815.

10.1039/D3TC02063K

Methylthiolation of Acenes: Change of Crystal Structure from Herringbone to Rubrene-like Pitched π-Stacking Structure

Cryst. Growth Des., 2023, 23, 5941–5949.

10.1021/acs.cgd.3c00525

Surface anisotropic magnetoresistance in the antiferromagnetic semiconductor CrSb2

Phys. Rev. B, 2023, 107, L180405.

10.1103/PhysRevB.107.L180405

Solution-Processable Ultrapure-Blue Light-Emitting Electrochemical Cells

Adv. Opt. Mater., 2023, 11, 2301119.

10.1002/adom.202301119

Sumanene-stacked supramolecular polymers. Dynamic, solvation-directed control

Chem. Commun., 2023, 59, 9595–9598.

10.1039/D3CC02990E

Diastereoselective Rotaxane Synthesis with Pillar[5]arenes via Co-crystallization and Solid State Mechanochemical Processes

J. Am. Chem. Soc., 2023, 145, 15324–15330.

10.1021/jacs.3c02919

Comprehensive Ab Initio Investigation of the Phase Diagram of Quasi-One-Dimensional Molecular Solids

Phys. Rev. Lett. , 2-23, 131, 036401.

10.1103/PhysRevLett.131.036401

Reactions of Tetra(o-tolyl)diborane(4) with Organic Azides: Formation of Fluorescent Boron-Fused Hexazenes

Chem. Eur. J., 2023, 29, e202302027.

10.1002/chem.202302027

Induction of Chirality on Nanographenes

Chem. Asian J., 2023, 18, e202300126.

10.1002/asia.202300126

Negative Homotropic Cooperativity in Guest Binding of a Trisporphyrin Double Cleft

Chem. Eur. J., 2023, 29, e202300107.

10.1002/chem.202300107

High-energy-resolution angle-resolved inverse-photoelectron spectroscopy apparatus for damage-free measurements of conduction band structures of functional materials

Rev. Sci. Instrum., 2023, 94, 063903.

10.1063/5.0138204

A straightforward method using the sign of the piezoelectric coefficient to identify the ferroelectric switching mechanism

Sci. Rep., 2023, 13, 8810.

10.1038/s41598-023-34923-0

Chiral superconductivity in UTe2 probed by anisotropic low-energy excitations

Nat. Commun., 2023, 14, 2966.

10.1038/s41467-023-38688-y

Two superconducting states with time-reversal symmetry breaking in FeSe1-xSx

Proc. Natl. Acad. Sci. USA, 2023, 120, e2208276120.

10.1073/pnas.2208276120

Statically and dynamically flexible hydrogen-bonded frameworks based on 4,5,9,10-tetrakis(4-carboxyphenyl)pyrene

Chem. Commun., 2023, 59, 7224–7227.

10.1039/D3CC01877F

Synthesis and structural evaluation of closed-shell folded and open-shell twisted hexabenzo[5.6.7]quinarene

Chem. Commun., 2023, 59, 7379–7382.

10.1039/D3CC02157B

Creation of a Field-Induced Co(II) Single-Ion Magnet by Doping into a Zn(II) Diamagnetic Metal–Organic Framework

Small, 2023, 19, 2301966.

10.1002/smll.202301966

A Dicyanomethyl Radical Conjugated with a Pyridylamino Group: Combining Radical-based Dynamic Covalent Chemistry and Coordination Chemistry

Angew. Chem. Int. Ed., 2023, 62, e202302498.

10.1002/anie.202302498

One-Shot Construction of BN-Embedded Heptadecacene Framework Exhibiting Ultra-narrowband Green Thermally Activated Delayed Fluorescence

J. Am. Chem. Soc., 2023, 145, 11504–11511.

10.1021/jacs.3c02873

Efficient synthesis and unit-selective π-extension of π-fused [4.3.3]propellane as chiral building blocks

Chem. Commun., 2023, 59, 7080–7083.

10.1039/d3cc01809a

Quantum oscillations in the centrosymmetric skyrmion-hosting magnet

Phys. Rev. B, 2023, 107, 104421.

10.1103/PhysRevB.107.104421

Flattened 1D fragments of fullerene C60 that exhibit robustness toward multi-electron reduction

Nat. Commun., 2023, 14, 2741.

10.1038/s41467-023-38300-3

Allosteric Signal-Amplifcation Sensing of Peptides with Cyclodextrin-Polymer Conjugates in Aqueous Media

ACS Appl. Polym. Mater., 2023, 5, 3653–3660.

10.1021/acsapm.3c00315

Stereoselective Synthesis and Characterization of Indenone Azine-Based Electron-Accepting π-Conjugated Systems

Chem. Eur. J., 2023, 29, e202300181.

10.1002/chem.202300181

Collective bending motion of a two-dimensionally correlated bowl-stacked columnar liquid crystalline assembly under a shear force

Sci. Adv., 2023, 9, eadg8202.

10.1126/sciadv.adg8202

A novel high-current, high-resolution, low-kinetic-energy electron source for inverse photoemission spectroscopy

Rev. Sci. Instrum., 2023, 94, 043908.

10.1063/5.0138512

Scattering mechanism of hole carriers in organic molecular semiconductors deduced from analyses of terahertz absorption spectra using Drude–Anderson model

Appl. Phys. Lett., 2023, 120, 053302.

10.1063/5.0073133

High-speed hybrid complementary ring oscillators based on solution-processed organic and amorphous metal oxide semiconductors

Commun. Mater., 2023, 4, 4.

10.1038/s43246-023-00331-0

Speed Tuning of the Formation/Dissociation of a Metallorotaxane

Angew. Chem. Int. Ed., 2023, 62, e202217048.

10.1002/anie.202217048

Synthesis of amphiphilic chiral salen complexes and their conformational manipulation at the air–water interface

Dalton Trans., 2023, 52, 260–268.

10.1039/D2DT03201E

Synthesis and Late-Stage Diversification of BN-Embedded Dibenzocorannulenes as Efficient Fluorescence Organic Light-Emitting Diode Emitters

Chem. Eur. J., 2023, 29, e202202627.

10.1002/chem.202202627

Double dome structure of the Bose–Einstein condensation in diluted S = 3/2 quantum magnets

Nat. Commun., 2023, 14, 1260.

10.1038/s41467-023-36725-4

Anisotropic enhancement of lower critical field in ultraclean crystals of spin-triplet superconductor UTe2

Phys. Rev. Res., 2023, 5, L022002.

10.1103/PhysRevResearch.5.L022002

Preferential orientation of anisotropic polythiophene rods toward macroscopic chain ordering

Mol. Sys. Des. Eng., 2023, 8, 316–322.

10.1039/D2ME00204C

Thermal Transformation of Polyacrylonitrile Accelerated by the Formation of Ultrathin Nanosheets in a Metal−Organic Framework

ACS Macro Lett., 2023, 12, 415–420.

10.1021/acsmacrolett.3c00072

Bis(triarylmethylium)-type Macrocyclic Dications: Mechanochromic Emission Extending to the Red Region

ChemPlusChem, 2023, 88, e202300110.

10.1002/cplu.202300110

Exceptionally Flexible Quinodimethanes with Multiple Conformations: Polymorph-Dependent Colour Tone and Emission of Crystals

Mater. Chem. Front., 2023, 7, 1591–1598.

10.1039/D2QM01199A

Enhancement of NIR-Absorbing Ability of Bis(diarylmethylium)-Type Dicationic Dyes Based on an Ortho-Substitution Strategy

Chem. Eur. J., 2023, 29, e202203899.

10.1002/chem.202203899

Deprotonation-Induced and Ion-Pairing-Modulated Diradical Properties of Partially Conjugated Pyrrole-Quinone Conjunction

J. Am. Chem. Soc., 2023, 145, 8122–8129.

10.1021/jacs.3c01025

A Double Heterohelicene Composed of Two Benzo[b]phenothiazine Exhibiting Intense Room-Temperature Circularly Polarized Phosphorescence

J. Mater. Chem. C, 2023, 11, 4846–4854.

10.1039/d3tc00871a

Synthesis and Properties of a Through-Space Interacting Diradicaloid

Precis. Chem., 2023, 1, 183–191.

10.1021/prechem.3c00024

Vapor-Phase Indium Intercalation in van der Waals Nanofibers of Atomically Thin W6Te6 Wires

ACS Nano, 2023, 17, 5561–5569.

10.1021/acsnano.2c10997

Ion-gel-based light-emitting devices using transition metal dichalcogenides and hexagonal boron nitride heterostructures

Jpn. J. Appl. Phys., 2023, 62, SC1026.

10.35848/1347-4065/acaeb2

Substituent-Dependent Photoexcitation Processes of π-Stacked Ion Pairs

Chem. Eur. J. , 2023, 29, e202203957.

10.1002/chem.202203957

Synthesis of Supramolecular A8Bn Miktoarm Star Copolymers by Host–Guest Complexation

Angew. Chem. Int. Ed., 2023, 62, e202219001.

10.1002/anie.202219001

Anion-Responsive Boron-Spiro-Centered π-Electronic Systems That Form Ion-Pairing Assemblies

Org. Lett., 2023, 25, 1120–1125.

10.1021/acs.orglett.3c00073

Lanthanide and Actinide Ion Complexes Containing Organic Ligands Investigated by Surface-Enhanced Infrared Absorption Spectroscopy

Inorg. Chem., 2023, 62, 474–486.

10.1021/acs.inorgchem.2c03618

Supramolecular Chiral Sensing by Supramolecular Helical Polymers

Chem. Commun., 2023, 59, 2421–2424.

10.1039/d2cc06502a

Bulk evidence of anisotropic s-wave pairing with no sign change in the kagome superconductor CsV3Sb5

Nat. Commun., 2023, 14, 667.

10.1038/s41467-023-36273-x

Photocured Liquid-Crystalline Polymer Electrolytes with 3D Ion Transport Pathways for Electromechanical Actuators

ACS Appl. Mater. Interfaces, 2023, 15, 4495–4504.

10.1021/acsami.2c19382

Dibenzotropylium-Capped Orthogonal Geometry Enabling Isolation and Examination of a Series of Hydrocarbons with Multiple 14π-Aromatic Units

J. Am. Chem. Soc., 2023, 145, 2596–2608.

10.1021/jacs.2c12574

Easily Switchable 18π-, 19π-, and 20π-Conjugation of Diazaporphyrin Double-Pincer Bispalladium Complexes

Angew. Chem. Int. Ed, 2023, 62, e202300437.

10.1002/anie.202300437

Spiroborate-Based Host Materials with High Triplet Energies and Ambipolar Charge-Transport Properties

Angew. Chem. Int. Ed., 2023, 62, e202217512.

10.1002/anie.202217512

Near-Infrared-Responsive Hydrocarbons Designed by π-Extension of Indeno[1,2,3,4-pgra]perylene at the 1,2,12-Positions

Chem. Eur. J., 2023, 29, e202300249.

10.1002/chem.202300249

One-dimensional stacking array of 10,20-diphenyl-5,15-diazaporphyrin metal complexes

J. Porphyrins Phthalocyanines, 2023, 27, 1035–1041.

10.1142/S1088424622500997

Synthesis of Twisted [n]Cycloparaphenylene by Alkene Insertion

Angew. Chem. Int. Ed., 2023, 62, e2022149.

10.1002/anie.202214960

Dinaphthooxepine Bisimide Undergoes Oxygen Extrusion Reaction upon Electron Injection at Room Temperature

Org. Lett., 2023, 25, 282–287.

10.1021/acs.orglett.2c04173

Charge-Segregated Stacking Structure with Anisotropic Electric Conductivity in NIR-Absorbing and Emitting Positively Charged π-Electronic Systems

Angew. Chem. Int. Ed., 2023, 62, e202216013.

10.1002/anie.202216013

Double helices of dissymmetrical α,α′-disubstituted tripyrrins

Org. Biomol. Chem., 2023, 21, 1158–1162.

10.1039/D2OB02125K

Single Crystalline, Non-stoichiometric Cocrystals of Hydrogen-Bonded Organic Frameworks

Angew. Chem. Int. Ed., 2023, 62, e202215836.

10.1002/anie.202215836

Isomeric effect of naphthyl spacers on structures and properties of isostructural porous crystalline frameworks

Mater. Chem. Front., 2023, 7, 106–116.

10.1039/D2QM01091G

Ultra-Narrowband Blue Multi-Resonance Thermally Activated Delayed Fluorescence Materials

Adv. Sci., 2023, 10, 2205070.

10.1002/advs.202205070

Computational Studies on the Structures of Nanographenes with Various Edge Functionalities

ChemPhysChem, 2023, 24, e202200465.

10.1002/cphc.202200465

Diazazethrene Bisimide: A Strongly Electron-Accepting π-System Synthesized via the Incorporation of both Imide Substituents and Imine-type Nitrogen Atoms into Zethrene

Chem. Sci., 2023, 14, 635–642.

10.1039/D2SC05992D

Sequential Multiple Borylation Toward an Ultrapure Green Thermally Activated Delayed Fluorescence Material

J. Am. Chem. Soc., 2023, 145, 1505–1511.

10.1021/jacs.2c10946

Flapping motion as a fluorescent probe for assembly process involving highly viscous liquid-like cluster intermediates during evaporative crystallization

Photochem. Photobiol. Sci., 2023, 22, 371–378.

10.1007/s43630-022-00321-0

Uncovered Effects of thieno[2,3-b]thiophene Substructure in a Tetrathienoacene Backbone: Reorganization Energy and Intermolecular Interaction

Chem. Mater., 2023, 35, 280–288.

10.1021/acs.chemmater.2c03160

Stacked antiaromaticity in the π-congested space between the aromatic rings in the anthracene dimer

J. Phys. Org. Chem., 2023, 36, e4451.

10.1002/poc.4451
招待講演

Exotic Aromaticity of Porphyrin Analogues

有機カチオン化学の開拓と機能探究

Exotic Aromaticity of Porphyrin Analogues

Exotic Aromaticity in Porphyrin Analogues

Exotic Aromaticity in Porphyrin Analogues

偏極中性子反射率測定による新規トポロジカル強磁性表面の直接観測

π共役骨格の配置を指針とした新規有機分子の創出

Chiroptical properties and multifold arylation of pillar[n]arenes

ポルフィリン類縁体の非古典的な芳香族性

大環状金錯体を経由した多重官能基化シクロパラフェニレン類の合成と機能

タンデムボラFriedel-Crafts反応を鍵とした次世代有機EL材料の開発

著書・総説・解説

Synthesis and Functional Control of Near-infrared Electrochromic Molecules Based on Redox-active Para-quinodimethane Scaffolds

Crystal Engineering, Electron Conduction, and Molecular Recognition and Reactivity by Chalcogen Bonds in Tetracyanoquinodimethanes Fused with [1,2,5]Chalcogenadiazoles

π-Electronic ion pairs: building blocks for supramolecular nanoarchitectonics via iπ-iπ interactions

Alignment and Dynamic Inversion of the Planar Chirality in Pillar[n]arenes

Cooperativity in molecular recognition of feet-to-feet-connected biscavitands

Host-Guest Behavior of Pillar[n]arene-Based Supramolecular Assemblies

Closed-shell and open-shell dual nature of singlet diradical compounds