Achievements

Group

Category

2024
Original papers

Non-threaded and rotaxane-type threaded wheel–axle assemblies consisting of dinickel(II) metallomacrocycle and dibenzylammonium axle

Commun. Chem. 2024, 7, 166 .

10.1038/s42004-024-01246-8

Direct evidence for a carbon–carbon one-electron σ-bond

Nature 2024,, in press .

10.1038/s41586-024-07965-1

Dithieno[3,2-b;2',3'-f]phosphepinium-Based Near-Infrared Fluorophores: px-π* Conjugation Inherent to Seven-Membered Phosphacycles

Angew. Chem. Int. Ed. 2024, 63, e202410204 .

10.1002/anie.202410204

Sulfur-Bridged Cationic Diazulenomethenes: Formation of Charge-Segregated Assembly with High Charge-Carrier Mobility

J. Am. Chem. Soc. 2024, 146, 22642–22649 .

10.1021/jacs.4c07122

Incorporation of ESIPT into Pillar[5]arene for Solid-State Dual Emission Responsive to n-Hexane Vapor

Bull. Chem. Soc. Jpn. 2024,, in press .

10.1093/bulcsj/uoae093

Radical reactivity of antiaromatic Ni(II) norcorroles with azo radical initiators

Beilstein J. Org. Chem. 2024, 20, 1967–1972 .

10.3762/bjoc.20.172

Synthesis and reactivity of the di(9-anthryl)methyl radical

Beilstein J. Org. Chem. 2024, 20, 2254–2260 .

10.3762/bjoc.20.193

On-surface Synthesis of Triaza[5]triangulene through Cyclodehydrogenation and its Magnetism

Angew. Chem. Int. Ed. 2024, 63, e202411893 .

10.1002/anie.202411893

Ion-Pairing Assemblies of Anion-Responsive π-Electronic Systems That Have Noncovalently Assisted Expanded Planar Region

Chem. Eur. J. 2024, 30, e202401932 .

10.1002/chem.202401932

Oxidation of Weakly Interacting Diradicals: An Approach for Strong and Tunable Near-Infrared-Absorbing Dyes Based on Small Chromophores

J. Phys. Chem. Lett. 2024, 15, 9175–9182 .

10.1021/acs.jpclett.4c02212

Twist along Central C-C Bonds in a Series of Fully π-Fused Propellanes

Chem. Eur. J. 2024, 30, e202402828 .

10.1002/chem.202402828

Rational bottom-up synthesis of sulphur-rich porous carbons for single-atomic platinum catalyst supports

Green Chem. 2024, 26, 8758–8767 .

10.1039/d4gc02055c

Multidimensional Dynamic Control of Supramolecular Phthalocyanine Gear: A Self-Assembly System Responding to Solvent, Temperature, and Hydrostatic Pressure

ACS Omega 2024, 9, 34719–34724 .

10.1021/acsomega.4c03584

Synthesis, Solid State Structures, and Properties of Linear and Tripodal Flexible Molecules with Pyrazinopyrazine Moieties

Chem. Lett. 2024, 53, upae140 .

10.1093/chemle/upae140

Quinoidal pi-extension of dipyranylidene derivatives: towards efficient dopants for n-type organic semiconductors

Org. Chem. Front. 2024,, in press .

10.1039/D4QO00961D

MT-pyrene-Based Conductive Radical Cation Salts: Crystal and Electronic Structure and Transport Properties

Cryst. Growth Des. 2024, 24, 5826–5833 .

10.1021/acs.cgd.4c00689

Synthesis of Aza[n]helicenes up to n=19: Hydrogen-bond-assisted Solubility and Benzannulation Strategy

J. Am. Chem. Soc. 2024, 146, 17428–17437 .

10.1021/jacs.4c05156

Benzannulated Double Aza[9]helicenes: Synthesis, Structures, and (Chir)optical Properties

Chem. Asian J. 2024, 19, e202400134 .

10.1002/asia.202400134

Synthesis and Dynamic Behaviors of 5,7,8,10-Tetraphenyl-1,14-dianilinotripyrrins

Synthesis 2024, 56, 1999–2004 .

10.1055/a-2314-1715

An n-type semiconducting diazaporphyrin-based hydrogen-bonded organic framework

Chem. Sci. 2024,, in press .

10.1039/D4SC03455D

Ratiometric Chemosensors That Are Capable of Quantifying Hydrostatic Pressure Stimulus: A Case of Porphyrin Tweezers

ACS Phys. Chem. Au 2024, 4, 510–521 .

10.1021/acsphyschemau.4c00025

Pillar[5]arenes decorated with six-membered-ring aromatics at all the substitution positions

Chem. Sci. 2024,, in press .

10.1039/d4sc01042f

Self-Inclusion Complexation of Electron-Accepting Guest into Electron-Donating Cyclic Host by Photoexcitation

Angew. Chem. Int. Ed. 2024, 63, e202404409 .

10.1002/anie.202404409

Exciplex Formation by Complexation of an Electron-Accepting Guest in an Electron-Donating Pillar[5]arene Host Liquid

J. Am. Chem. Soc. 2024, 146, 9828–9835 .

10.1021/jacs.3c14582

Structural-Change-Induced Two-Stage Redox Behavior of Pentacenebisquinodimethane with Tricolor Chromism

Chem. Asian J. 2024,, in press .

10.1002/asia.202400316

Cation-Stacking Approach Enabling Interconversion between Bis(xanthylium) and its Reduced Species

Chem. Eur. J. 2024,, in press .

10.1002/chem.202401683

Synthesis and Chiroptical Properties of Cyclic Anthraquinodimethane Dimer Using Au-Templated Method

Chem. Lett. 2024, 53, upae102 .

10.1093/chemle/upae102

Thermal Equilibrium between Quinoid/Biradical Forms Enhancing Electrochemical Amphotericity

Chem. Eur. J. 2024,, in press .

10.1002/chem.202400916

Extended 9b-Boraphenalenes: Synthesis, Structure, and Physical Properties

J. Am. Chem. Soc. 2024,, in press .

10.1021/jacs.4c02407

Amplification sensing manipulated by a sumanene-based supramolecular polymer as a dynamic allosteric effector

Sci. Rep. 2024, 14, 12534 .

10.1038/s41598-024-63304-4

peri-Benzo-Diindenotetracenyl: Helically π-Extended Allyl Radical with Robust Stability

Chem. Eur. J. 2024, 30, e202401353 .

10.1002/chem.202401353

End-to-End Bent Perylene Bisimide Cyclophanes by Double Sulfur Extrusion

J. Am. Chem. Soc. 2024,, in press .

10.1021/jacs.4c05358

Enhanced emergent electromagnetic inductance in Tb5Sb3 due to highly disordered helimagnetism

Commun. Phys. 2024, 7, 159 .

10.1038/s42005-024-01656-z

Synthesis of sterically congested double helicene by alkyne cycloisomerization

Chem. Commun. 2024,, in press .

10.1039/D4CC01573H

Theoretical investigation on the effect of radical substituents on the open-shell character of polycyclic aromatic hydrocarbon

New. J. Chem. 2024, 48, 8683–8689 .

10.1039/D4NJ00555D

Photo-responsive Hydrogen-Bonded Molecular Networks Capable of Retaining Crystalline Periodicity after Isomerization

Angew. Chem. Int. Ed. 2024,, in press .

10.1002/anie.202404700

Completely solvent-free synthesis of double heterohelicenes and their further ring fusion using mechanochemical reaction

RSC Mechanochem. 2024,, in press .

10.1039/D4MR00033A

Optically Distinguishable Electronic Spin-isomers of a Stable Organic Diradical

ACS Cent. Sci. 2024, 10, 890–898 .

10.1021/acscentsci.4c00284

Efficient Deep-Blue Multiple-Resonance Emitters Based on Azepine-Decorated ν-DABNA for CIEy below 0.06

Adv. Mater. 2024,, in press .

10.1002/adma.202402905

Molecular beam epitaxy of superconducting FeSexTe1−x thin films interfaced with magnetic topological insulators

Phys. Rev. Materials 2024, 8, L041801 .

10.1103/PhysRevMaterials.8.L041801

Strongly pinned skyrmionic bubbles and higher-order nonlinear Hall resistances at the interface of Pt/FeSi bilayer

Phys. Rev. Materials 2024, 8, 044407 .

10.1103/PhysRevMaterials.8.044407

Norcorroles as antiaromatic π-electronic systems that form dimension-controlled assemblies

Chem. Sci. 2024,, in press .

10.1039/d4sc01633e

Substitution-pattern- and counteranion-dependent ion-pairing assemblies of heteroporphyrin-based π-electronic cations

Chem. Commun. 2024, 60, 4190–4193 .

10.1039/d4cc00806e

Design and enantioselective synthesis of 3D π-extended carbohelicenes for circularly polarized luminescence

Nat. Synth. 2024,, in press .

10.1038/s44160-024-00527-3

Solvent-free synthesis and chiroptical properties of a C–N axially chiral cruciform dimer of benzo[b]phenoxazine

Chem. Commun. 2024,, in press .

10.1039/D4CC00977K

Compensated Ferrimagnets with Colossal Spin Splitting in Organic Compounds

Phys. Rev. Lett. 2024, 132, 156502 .

10.1103/PhysRevLett.132.156502

Synthesis and properties of doubly diphenylene-fused benzopyrrolo[1,4]diazocine with a [7-8-7] successive ring-fused structure

Chem. Lett. 2024, 53, upae021 .

10.1093/chemle/upae021

Highly efficient multi-resonance thermally activated delayed fluorescence material toward a BT.2020 deep-blue emitter

Nat. Commun. 2024, 15, 2361 .

10.1038/s41467-024-46619-8

Combined experimental and theoretical studies on glasslike transitions in the frustrated molecular conductors θ − ( BEDT − TTF ) 2 M M ′ ( SCN ) 4

Phys. Rev. Res. 2024, 6, 023003 .

10.1103/PhysRevResearch.6.023003

Topological stability of spin textures in Si/Co-doped helimagnet FeGe

J. Phys. Mater. 2024, 7, 025009 .

10.1088/2515-7639/ad2ec4

Close Stacking of Antiaromatic Ni(II) Norcorrole Originating from a Four-Electron Multicentered Bonding Interaction

J. Am. Chem. Soc. 2024,, in press .

10.1021/jacs.4c01142

Facile and controllable chemical doping of conducting polymers with an ionic liquid dopant

Appl. Phys. Express 2024, 17, 031002 .

10.35848/1882-0786/ad2f66

Defect-Induced Low-Energy Majorana Excitations in the Kitaev Magnet α−RuCl3

Phys. Rev. X 2024, 14, 011045 .

10.1103/PhysRevX.14.011045

Majorana-Fermion origin of the planar thermal Hall effect in the Kitaev magnet α-RuCl3

Sci. Adv. 2024, 10, eadk3539 .

10.1126/sciadv.adk3539

Electron spin resonance spectroscopic evidence of the transition to a spin-singlet state in the monomer Mott insulator (BEDT-TTF)Cu[N(CN) 2 ] 2

Phys. Rev. B 2024, 109, 125115 .

10.1103/PhysRevB.109.125115

Solid-State Emissive Pillar[6]arene Derivatives Embedded with Nitrogen into Bridging Moieties

Chem. Asian J. 2024, 19, e202400106 .

10.1002/asia.202400106

Alkoxylated Fluoranthene-Fused [3.3.3]Propellanes: Facile Film Formation against High π-Core Content

Chem. Asian J. 2024, 19, e202400080 .

10.1002/asia.202400080

Silapillar[n]arenes: Their Enhanced Electronic Conjugation and Conformational Versatility

J. Am. Chem. Soc. 2024, 146, 4695–4703 .

10.1021/jacs.3c12093

Spin-Spin Interaction in a Highly Stable Neutral Diradical: σ-Boned Dimer of Trioxotriangulene

Chem. Lett. 2024, 53, upae030 .

10.1093/chemle/upae030

A Triply Linked Porphyrin-Norcorrole Hybrid with Singlet Diradical Character

Angew. Chem. Int. Ed. 2024, 63, e202401233 .

10.1002/anie.202401233

A Novel N-Type Molecular Dopant with A Closed-Shell Electronic Structure Applicable to the Vacuum-Deposition Process

Adv. Mater. 2024,, in press .

10.1002/adma.202311047

Benzoquinone-Imidazole Hybrid Organic Anolyte for Aqueous Redox Flow Battery

Chem. Commun. 2024, 60, 878–880 .

10.1039/D3CC04840C

Interaction strength in molecular junctions consisting of π-stacked antiaromatic molecules

J. Mater. Chem. C 2024, 12, 1640–1643 .

10.1039/D3TC04166B

Friedel-Crafts Acylation for Accessing Multi-Bridge-Functionalized Large Pillar[n]arenes

Angew. Chem. Int. Ed. 2024, 63, e202318268 .

10.1002/anie.202318268

Stable planar chirality of arylated Pillar[6]arene and its thermal response

Tetrahedron Lett. 2024, 135, 154891 .

10.1016/j.tetlet.2023.154891

Circularly polarized luminescence from a common alkoxy pillar[5]arene and its co-aggregates with π-conjugated rods

Aggregate 2024,, in press .

10.1002/agt2.482

Size-Selective Capture of Fluorocarbon Gases and Storage of Volatile Halogenated Organic Vapors with Low Boiling Points by Molecular-Scale Cavities of Crystalline Pillar[n]quinones

Adv. Funct. Mater. 2023,, in press .

10.1002/adfm.202312304

Metallaantiaromaticity of 10-Platinacorrole Complexes

J. Am. Chem. Soc.2024, 146, 1396–1402 .

10.1021/jacs.3c10250

Evidence for an odd-parity nematic phase above the charge-density-wave transition in a kagome metal

Nat. Phys.2024, 20, 40–46 .

10.1038/s41567-023-02272-4

Enhanced solid-state phosphorescence of organoplatinum π-systems by ion-pairing assembly

Chem. Sci. 2024, 15, 964–973 .

10.1039/d3sc04564a
Invited lecture

Recent advances in smart chemosensors that can detect and quantify hydrostatic pressure

Open Frameworks Built though Hydrogen Bonds

Hydrogen bonds for constructing porous crystalline molecular frameworks

Synthesis of Aza[n]helicenes (n=9-19) and Systematic Studies on Their (Chir)Optical and Electrochemical Properties

Antiaromaticity of 8,10-Fused Iminoisocorroles

Metallaantiaromaticity of 10-Platinacorrole Complexes

π共役骨格の立体配置に基づく新規有機分子の合成と物性評価

有機カチオン化学の開拓

Beyond π-conjugation – 分子間の電子共役

Reviews Accounts

Electron Transport over 2D Molecular Materials and Assemblies

Long carbon–carbon bonds and beyond

非磁性絶縁体FeSiにおける強磁性トポロジカル表面状態の発現と強スピン-軌道結合物性

Crystal-Structure Control of Molecular Semiconductors by Methylthiolation: Toward Ultrahigh Mobility

Organoboron-based multiple-resonance emitters: synthesis, structure–property correlations, and prospects