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L. M. A. Ali, K. Miyagawa, H. N. Fukui, M. Onofre, K. Elcheikh, A. Morère, S. Clément, M. Gary-Bobo*, S. Richeter*, H. Shinokubo*

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Synthesis of meso-Free Decaphyrin(1.1.1.1.1.1.1.1.1.1) by a Hydrodebromination Protocol; Aromaticity and Solvent-Polarity Dependent Conformational Change

A. Nakai, H. Saito, H. Yorimitsu, T. Tanaka*, A. Osuka*

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M. Fujita, Y. Haketa, H. Tanaka, N. Yasuda, H. Maeda*

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Heteroatom-Incorporated Trimethylenemethane: Synthesis and Properties of Triphenylphenylnitroxide-(Nitronyl Nitroxide) Dyad

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A Molecule Having 13 Unpaired Electrons: Magnetic Property of a Gadolinium(III) Complex Coordinated with Six Nitronyl Nitroxide Radicals

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What defines a crystal structure? Effects of chalcogen atoms in 3,7-bis(methylchalcogeno)benzo[1,2-b:4,5-b′]dichalcogenophene-based organic semiconductors

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Dynamic Au–C σ-Bonds Leading to an Efficient Synthesis of [n]Cycloparaphenylenes (n = 9–15) by Self-Assembly

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Synthesis of Dibenzo[h,t]rubicene through Its Internally Dimethoxy-Substituted Precursor

M. Kato, N. Fukui,* H. Shinokubo*

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Y. Shoji, M. Kobayashi, A. Kosaka, R. Haruki, R. Kumai, S. Adachi, T. Kajitani, T. Fukushima

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M. Yoshida, T. Hirao, T. Haino*

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A. Nishiyama, T. Tanaka*

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Quinoxaline-annelated hexadehydro[12]annulene: use of a new building block to construct a hydrogen-bonded hexagonal molecular network

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1,3,6,8-Tetrakis(methylchalcogeno)pyrenes: Effects of Chalcogen Atoms on the Crystal Structure and Transport Properties

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Efficient and Chiral Electroluminescence from In-Plane Heterostructure of Transition Metal Dichalcogenide Monolayers

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Control of dual emission behaviour of µ-oxo-bridged Si(IV) corrole dimers by substituent bulkiness

K. Yamagata, K. Ueta, A. Nakai, A. Osuka, T. Tanaka*

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Synergistic Enhancement of Hydrogen-Bonding and Charge-Transfer Interactions in a Crystal of an Anthranol–Acridine Dyad Comprised of a Hydrogen-Bonded Chain Aggregate

Y. Hirao*, H. Isobe, K. Hosoi, T. Kubo*

J. Phys. Chem. C 2022, 126, 10940–10946 .

Development of Pure Green Thermally Activated Delayed Fluorescence Material by Cyano Substitution

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Optical conductivity spectra of charge-crystal and charge-glass states in a series of θ-type BEDT-TTF compounds

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Crystals 2022, 12, 831 .

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Y. Matsui*, Y. Yokoyama, T. Ogaki, K. Ishiharaguchi, A. Niwa, M. Saigo, K. Miyata, K. Onda*, H. Naito*, H. Ikeda*

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Remarkable Piezofluorochromism of an Organoboron Complex Containing [2.2]Paracyclophane

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Electric-Field-Induced Metal-Insulator Transition and Quantum Transport in Large-Area Polycrystalline MoS2 Monolayers

H. Ou, T. Yamada, M. Mitamura, Y. Edagawa, T. D. Matsuda, K. Yanagi, C.-H. Chen, L.-J. Li, T. Takenobu*, J. Pu*

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Ultrafast Singlet Fission and Efficient Carrier Transport in a Lamellar Assembly of Bis[(trialkoxyphenyl)ethynyl]pentacene

Hayato Sakai, Keisuke Yoshino, Yoshiaki Shoji, Takashi Kajitani, Jiang Pu, Takanori Fukushima, Taishi Takenobu, Nikolai V. Tkachenko, and Taku Hasobe

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π-Expansion of 2,3,6,7-Tetraazanaphthalene with Two Embedded Heptagons: Highly Twisted Structure and Lone-Pair/π* Interaction in the Crystal

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Effects of Conformation on Doping Efficiency in π-Extended Bipyranylidene Molecules: Relationship between Molecular Structure and Electron-Doping Ability for Developing n-Type Organic Thermoelectrics

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Large Enhancement of Single Molecular Conductance of Molecular Wire through a Radical Substituent

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Comparison of the charge-crystal and charge-glass state in geometrically frustrated organic conductors studied by fluctuation spectroscopy

T. Thomas, T. Thyzel, H. Sun, J. Müller, K. Hashimoto, T. Sasaki, and H. M. Yamamoto

Phys. Rev. B 2022, 105, 205111 .

Hybrid Chiral MoS2 Layers for Spin-polarized Charge Transport and Spin-dependent Electrocatalytic Applications

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Solid-State Assembly by Chelating Chalcogen Bonding in Quinodimethane Tetraesters Fused with a Chalcogenadiazole

Y. Ishigaki, K. Asai, H.-P. Jacquot de Rouville, T. Shimajiri, J. Hu, V. Heitz, T. Suzuki*

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Chalcogen Bond versus Halogen Bond: Changing Contributions in Determining the Crystal Packing of Dihalobenzochalcogenadiazoles

Y. Ishigaki, K. Shimomura, K. Asai, T. Shimajiri, T. Akutagawa, T. Fukushima, T. Suzuki*

Bull. Chem. Soc. Jpn. 2022, 95, 522–531 .

Copper(II) Complexes of 10,20-Diaryl-5,15-diazaporphyrin: Alternative Synthesis, Excited State Dynamics, and Substituent Effect on the 1O2-Generation Efficiency

H. Ochiai, T. Miura, T. Ikoma, H. Nakano, Y. Matano*

Bull. Chem. Soc. Jpn. 2022, 95, 427–432 .

Spatiotemporal dynamics of supramolecular polymers by in situ quantitative catalyst-free hydroamination

M. Tan, M. Takeuchi,* A. Takai*

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Synthesis of π-Extended Thiele’s and Chichibabin’s Hydrocarbons and Effect of the π-Congestion on Conformations and Electronic States

T. Nishiuchi*, S. Aibara, H. Sato, T. Kubo*

J. Am. Chem. Soc. 2022, 144, 7479–7488 .

Synthesis and Tautomerization of 5-Azaporphyrinium Cations

A. Takiguchi, H. Shinokubo*

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Chiral Supramolecular Polymer Formed via Host-Guest Complexation of an Octaphosphonate Biscavitand and a Chiral Diammonium Guest

K. Hamada, D. Shimoyama, T. Hirao, T. Haino*

Bull. Chem. Soc. Jpn. 2022, 95, 621–627 .

5-Thiaporphyrinium Cation: Effect of Sulphur Incorporation on Excited State Dynamics

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Chem. Commun. 2022, 58, 5956–5959 .

Formation of a Two-Dimensional Electronic System in Laterally Assembled WTe Nanowires

Hiroshi Shimizu, Jiang Pu, Zheng Liu, Hong En Lim, Mina Maruyama, Yusuke Nakanishi, Shunichiro Ito, Iori Kikuchi, Takahiko Endo, Kazuhiro Yanagi, Yugo Oshima, Susumu Okada, Taishi Takenobu, Yasumitsu Miyata

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Tunable Solid-State Thermochromism: Alkyl Chain Length-Dependent Conformational Isomerization of Bianthrones

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Sterically Frustrated Aromatic Enes with Various Colors Originating from Multiple Folded and Twisted Conformations in Crystal Polymorphs

T. Nishiuchi,* S. Aibara, T. Yamakado, R Kimura, S. Saito, H. Sato, T. Kubo*

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A carbon-functionality-appended diborylacetylene available for a component of organic synthesis and OLEDs

T. Tsukada, Y. Shoji*, K. Takenouchi, H. Taka, T. Fukushima*

Chem. Commun. 2022, 58, 4973–4976 .

Microscopic observation of efficient intergrain charge transport processes in organic transistors of semicrystalline poly(3-hexylthiophene)

S. Kuroda*, H. Tanaka, Y. Shimoi

Appl. Phys. Express 2022, 15, 041004 .

Diverse Crystal Structures of Ion Pairs Consisting of Oxaporphyrinium Cations and Pentacyanocyclopentadienide

A. Takiguchi, H. Tanaka, H. Maeda,* H. Shinokubo*

Bull. Chem. Soc. Jpn. 2022, 95, 796–801 .

Host-Guest Complexation of Bisporphyrin Cleft and Electron-Deficient Aromatic Guests

N. Hisano, T. Haino*

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Transient chirality inversion during racemization of a helical cobalt(III) complex

Y. Sakata, S. Chiba, S. Akine

Proc. Natl. Acad. Sci. USA 2022, 119, e2113237119 .

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Large Enhancement of Single Molecular Conductance of Molecular Wire by a Radical Substituent

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Chem. Eur. J. 2022, 28, e202104242 .

A Fully Conjugated Porphyrin–[36]Octaphyrin–Porphyrin Hybrid Tape Exhibiting Möbius Aromaticity

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Chem. Eur. J. 2022, 28, e202200328 .

Synthesis, Properties and Chemical Modification of a Persistent Triisopropylsilylethynyl Substituted Tri(9-anthryl)methyl Radical

T. Nishiuchi*, D. Ishii, S. Aibara, H. Sato, T. Kubo*

Chem. Commun. 2022, 58, 3306–3309 .

A dicyanomethyl radical stabilized by ferrocene: a new building block for radical-based dynamic covalent chemistry with redox activity

M. Ishimoto, D. Sakamaki,* H. Fujiwara*

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A strong hydride donating, acid stable and reusable 1,4-dihydropyridine for selective aldimine and aldehyde reductions

Y. Hirao*, H. Eto, M. Teraoka, T. Kubo*

Org. Bio. Chem. 2022, 20, 1671–1679 .

Magnetic Torque due to Anisotropic Diamagnetism in Neutral BEDT-TTF Crystals

S. Uji*, T. Terashima, S. Sugiura, S. Iguchi, T. Sasaki, K. Hashimoto, M. Shimozawa, N. Yoneyama, and R. Kato

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Tuning the Parity Mixing of Singlet-Septet Pairing in a Half-Heusler Superconductor

K. Ishihara, T. Takenaka, Y. Miao, Y. Mizukami, K. Hashimoto, M. Yamashita, M. Konczykowski, R. Masuki, M. Hirayama, T. Nomoto, R. Arita, O. Pavlosiuk, P. Wiśniewski, D. Kaczorowski, T. Shibauchi

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Nanowire-to-Nanoribbon Conversion in Transition-Metal Chalcogenides: Implications for One-Dimensional Electronics and Optoelectronics

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Thermodynamic evidence for a field-angle-dependent Majorana gap in a Kitaev spin liquid

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Involvement of structural dynamics in charge-glass formation in strongly frustrated molecular metals

T. Thomas, Y. Saito, Y. Agarmani, T. Thyzel, M. Lonsky, K. Hashimoto, T. Sasaki, M. Lang, and J. Müller*

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Dibenzodiazapyracylenes: Doubly N-Doped Cyclopenta-fused Polycyclic Molecules That Exhibit High Carrier Mobility

Y. Morimoto, Y. H. Koo, K. Otsubo, H. Kitakado, S. Seki,* A. Osuka, T. Tanaka*

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Bridging pico-to-nanonewtons with a ratiometric force probe for monitoring nanoscale polymer physics before damage

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Ratiometric Flapping Force Probe That Works in Polymer Gels

T. Yamakado, S. Saito*

J. Am. Chem. Soc. 2022, 144, 2804–2815 .

Probing a microviscosity change at the nematic-isotropic liquid crystal phase transition by a ratiometric flapping fluorophore

R. Kimura, H. Kitakado, T. Yamakado, H. Yoshida*, S. Saito*

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On-Surface Synthesis of Porphyrin-Complex Multi-Block Co-Oligomers by Defluorinative Coupling

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Molecular and Spin Structures of a Through-Space Conjugated Triradical System

T. Kodama, M. Aoba, Y. Hirao*, S. M. Rivero, J. Casado*, T. Kubo*

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Anthraquinodimethane Ring-Flip in Sterically Congested Alkenes: Isolation of Isomer and Elucidation of Intermediate through Experimental and Theoretical Approach

Y. Ishigaki*, T. Tadokoro, Y. Harabuchi, Y. Hayashi, S. Maeda*, T. Suzuki*

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Nitrogen Extrusion of Diazacorrphycenes to Azacorroles and Synthesis of Two Types of Copper 10-Azacorrole Complexes

A. Yagi, N. Okada, N. Fukui, H. Tanaka, T. Hatakeyama, H. Shinokubo*

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Late-Stage Modification of π-Electron Systems Based on Asymmetric Oxidation of Medium-Sized Sulfur-Containing Ring

M. Hayakawa, S. Horike, Y. Hijikata, K. Yasui, S. Yamaguchi, A. Fukazawa*

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Synthesis and optical properties of disiloxane-linked decathiophene and dodecathiophene polymers

J. Ohshita,* A. Ohta, S. Z. B. Saadom, Y. Adachi, H. Murakami, T. Haino

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Mechanism and Kinetics of Fluorescence Quenching of Fluorene-Endcapped Butatriene: A Microspectroscopic Study of the Discrete State Constructed in Microcrystals

Y. Hirao*, K. Ihara, Y. Ishibashi*, E. G. Tiu, T. Asahi, T. Kubo*

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Isolation and Structure Analysis of a Ni(II) Norcorrole Radical Anion

S. Ukai, N. Fukui, T. Ikeue, H. Shinokubo*

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Fold-in Synthesis of a Pentabenzopentaaza[10]circulene

Y. Matsuo, K. Kise, Y. Morimoto, A. Osuka, T. Tanaka*

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A Supramolecular Polymer Constituted of Antiaromatic Ni(II) Norcorroles

S. Ukai, A. Takamatsu, M. Nobuoka, Y. Tsutsui, N. Fukui, S. Ogi*, S. Seki*, S. Yamaguchi*, H. Shinokubo*

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A Heme-Acquisition Protein Reconstructed with a Cobalt 5-Oxaporphyrinium Cation and Its Growth-Inhibition Activity Toward Multidrug-Resistant Pseudomonas aeruginosa

A. Takiguchi, E. Sakakibara, H. Sugimoto, O. Shoji*, H. Shinokubo*

Angew. Chem. Int. Ed. 2022, 61, e202112456 .

Metallic Conduction and Carrier Localization in Two-Dimensional BEDO-TTF Charge-Transfer Solid Crystals

Hiroshi Ito, Motoki Matsuno, Seiu Katagiri, Shinji K. Yoshina, Taishi Takenobu, Manabu Ishikawa, Akihiro Otsuka, Hideki Yamochi, Yukihiro Yoshida, Gunzi Saito, Yongbing Shen and Masahiro Yamashita

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1,2,3-Tri(9-anthryl)benzene: Photophysical Properties and Solid-State Intermolecular Interactions of Radially Arranged, Congested Aromatic π-Planes

T. Nishiuchi*, H. Sotome*, K. Shimizu, H. Miyasaka*, T. Kubo*

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Enantiopure 2-(2-ethylhexyl)dinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophenes: synthesis, single crystal-structure and surprising lack of influence of stereoisomerism on thin-film structure and electronic properties

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Packing structures of (trialkylsilyl)ethynyl-substituted dinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophenes (DNTTs): effects of substituents on crystal structures and transport properties

K. Takimiya⁎, S. Usui, A. Sato, K. Kanazawa, K. Kawabata

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Five-fold Symmetric Pentaindolo- and Pentakis(benzoindolo)-Corannulenes: Unique Structural Dynamics Derived from the Combination of Helical- and Bowl-Inversions

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One-Shot Synthesis of Expanded Heterohelicene Exhibiting Narrowband Thermally Activated Delayed Fluorescence

S. Oda, B. Kawakami, Y. Yamasaki, R. Matsumoto, M. Yoshioka, D. Fukushima, S. Nakatsuka, T. Hatakeyama*

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Tetraaryldiborane(4) Can Emit Dual Fluorescence Responding to the Structural Change around the B–B Bond

Y. Shoji*, N. Tanaka, Y. Ikabata*, H. Sakai, T. Hasobe, N. Koch, H. Nakai, T. Fukushima

Angew. Chem. Int. Ed. 2022, 61, e202113549 .